His explanation of knocking is AMAZING:
It's because those engines like to squeeze the gas and air in a super tight piston-driven bear hug, and the gas can sometimes get too excited and prematurely explode inside the engine (presumably while muttering shameful apologies into its shoulder). When this happens, it causes a phenomenon known as detonation or "knocking." Even though the engine tries to reassure the gas that it's perfectly natural and isn't anything to be ashamed of, it still wouldn't mind if the gasoline got a little help with its "staying power," which comes in the form of higher octane ratings.